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Assessing risks associated with gases and vapours (INFO-RA2-4)

Land contamination can give rise to volatile contaminants which can pose a risk of harm to human health by asphyxiation or illness if inhaled. Vapours and gases such as methane may also pose a risk of fire or explosion.

ASTM

  • Standard Guide for Evaluating Potential Hazard as a result of Methane in the Vadose Zone. ASTM E2993-16. 2016 
  • Standard Guide for Risk-Based Corrective Action. ASTM, E2081-00. 2016.

Basement Information Centre

  • Basements: Ground gases and structural waterproofing. The basement Information Centre, 2021.

BRE

  • Construction of New Buildings on Gas-contaminated Land, BR212.  BRE, 1991. (INFO-RA-4a)
  • Protective measures for housing on gas-contaminated land. BRE Report 414. 2001.
  • Radon: Guidance on protective measures for new buildings, BR211. 2015. BRE. WITHDRAWN
  • Radon: Guidance on protective measures for new buildings, 2023, BRE.

BSI

  • Guidance on investigations for ground gas – permanent gases and volatile organic compounds (VOCs). BS 8576. BSI, 2013.
  • Code of Practice for the design of protective measures for methane and carbon dioxide ground gases in new buildings. BS8485. BSI. 2015. SUPERSEDED
  • Code of Practice for the design of protective measures for methane and carbon dioxide ground gases in new buildings, BS8485. BSI. 2019.

Chartered Institute of Environmental Health

  • The Local Authority Guide to Ground Gas. Wilson, S., Card, G. and Haines, S.: Chartered Institute of Environmental Health, London, 2008. - Out of Print

CIRIA

  • Methane: Its Occurrence and Hazards in Construction, R130. CIRIA,1993. (INFO-RA2-4b).
  • Protecting Development from Methane, R149. CIRIA,1995. (INFO-RA2-4c).
  • Interpreting Measurements of Gas in the Ground, R151. CIRIA, 1995. (INFO-RA2-4d).
  • Risk Assessment for Methane and Other Gases from the Ground, R152. CIRIA, 1995. (INFO-RA2-4e).
  • Assessing Risks Posed by Hazardous Ground Gases to Buildings. C665. CIRIA, 2007.
  • The VOC Handbook. Investigation, Assessing and Managing Risks from Inhalation of VOCs at Land Affected by Contamination. Baker et al. CIRIA C682, 2009.
  • Good practice on the testing and verification of protection systems for buildings against hazardous ground gases. Mallett, H. , Cox L, Wilson s, Corban M. CIRIA C735, 2014.
  • Guidance on the use of plastic membranes as VOC vapour barriers. Wilson, S., Abbot, A. and Mallett, H. CIRIA C748, 2014.
  • Retrofitting hazardous ground gas protection measures in existing or refurbished buildings. Wilson S, Sopp G, Mallett H and Card G. CIRIA C795, 2020.
  • A site guide for managing ground gases. Mortimer S, Wilson S and Corban M. CIRIA C801, 2021.

CL:AIRE

  • The utility of continuous monitoring in the detection and prediction of worst case ground gas concentration. RB13. CL:AIRE, 2011.
  • A pragmatic approach to Ground Gas Risk Assessment. RB17. CL:AIRE, 2012.
  • Complete continuous monitoring in underfloor voids. TB16. CL:AIRE 2018
  • Ground gas monitoring and "worst case" conditions. TB17. CL:AIRE, 2018
  • Continuous ground-gas monitoring and the lines of evidence approach to risk assessment. TB18. CL:AIRE, 2019
  • Video: Verification of Gas Protection Measures

Environment Agency

  • Vapour Transfer of Soil Contaminants, R&D Technical Report P5-018/TR. EA, 2002. (INFO-RA2-4h) (PDF, 1.6MB)
  • Landfill Gas Technical Guidance Note 7. Guidance on Monitoring Landfill Gas Surface Emissions. V2 2010.
  • ACUMEN-Assessing, Capturing and Utilising Methane from Expired and Non-operational Landfills. ACUMEN Project Report - Managing Landfill Gas at Closed and Historic Sites. EC Project ref. LIFE11 ENV/UK/402
  • GasSim (simulation tool for gas emissions and migration from landfill), 2012.

Ground Engineering

  • Reliability and Risk in Gas Protection Design. Wilson S. & Card G. Ground Engineering, January 1999.
  • Reliability and Risk in Gas Protection Design: 20 years on, Part 1. Wilson S., Card G. and Lucas J. Ground Engineering, August 2019.
  • Reliability and Risk in Gas Protection Design: 20 years on, Part 2. Wilson S., Card G. and Lucas J. Ground Engineering, September/October 2019.

Info4education

  • Passive Venting of Soil Gases Beneath Buildings. DETR/PIT, 1997. (INFO-RA2-4f) Volume 1 (Guide for Design)
  • Volume 2 (Computational Fluid Dynamics Modelling: Example Output) 

Land Contamination & Reclamation

  • Modular approach to analysing vapour migration into buildings in the UK. Wilson S. July 2008, Land Contamination & Reclamation 16(3).
  • Quantifying risks due to ground gas on brownfield sites. J.A Sladen, A. Parker and G.L.Dorrell. Land Contamination & Reclamation 9(2).

NHBC

  • Guidance on Evaluation of Development Proposals on Sites Where Methane and Carbon Dioxide are Present. 10627-R01(04). NHBC and RSK Group. NHBC , 2007.
  • Hazardous Ground Gas - An essential guide for housebuilders (NF94). NHBC, April 2023.

United States Environmental Protection Agency

  • Petroleum Hydrocarbons and Chlorinated Solvents Differ in their Potential Vapor Intrusion. USEPA, 2012
  • Technical Guide Addressing Petroleum Vapor Intrusion at Leaking Underground Storage Tank Sites. EPA510-R-15-001, USEPA, June 2015
  • Technical Guide for Assessing and Mitigating Vapor Intrusion Pathway from Subsurface Vapor Sources to Indoor Air. OSWER Publication 9200.2-154, USEPA, 2015

Others

  • Vertical screening distances for total petroleum hydrocarbon for vapour intrusion risk assessment at petroleum underground storage tank sites. Lahvis, M A. Quarterly Journal of Engineering Geology and Hydrogeology, 51, 3-12, 2017. 
  • Corrosion and puncture resistance of aluminium foil gas membranes beneath concrete slabs. Lucas J and Wilson S. Geosynthetics International, ISSN 1751-7613, Volume 27 Issue 4, August 2020. pp.451-459.
  • The Monitoring of Landfill Gas, Landfill Gas Monitoring Working Group report. IWM, 1998. (INFO-RA2-4g). This report is out of print but may be available from subscription libraries.
  • Gas protection measures for buildings. Methodology for the quantitative design of gas dispersal layers. Owen, R. and Paul, V. Proceedings of the Fifth International Conference – Polluted and Marginal Land. 1998
  • Ground Gas Handbook. Wilson S, Card G, Haines S. Whittles Publishing. 2009.

Ongoing Update of Ground Gas Handbook - Ground Gas Information Sheets:

  • Ground Gas information Sheet No 1. Using ternary plots for interpretation of gas monitoring results.
  • Ground Gas information Sheet No 2. Dissolved methane monitoring for ground gas risk assessment.
  • Ground Gas information Sheet No 3. Screening approach for landfill gas migration around landfill sites.
  • Ground Gas information Sheet No 4. Basement waterproofing and ground gas.
  • Ground Gas information Sheet No 5. Gas membranes and “compliance” with BS8485.
  • Ground Gas information Sheet No 6. Using purge and recovery tests in ground gas risk assessment.
  • Ground Gas information Sheet No. 9.  Multiple lines of evidence approach using continuous monitoring data.

Assessing risks to buildings and services (INFO-RA2-6)

Land contamination can pose risks to buildings in a number of ways. Volatile contaminants and gases can accumulate and cause explosion or fire. Foundations and buried services can be damaged by corrosive substances and contaminants such as steel slags can create unstable ground conditions through expansion causing structural damage.

  • Performance of Building Materials in Contaminated Land, BR255. BRE, 1994. (INFO-RA2-6a)
  • Risks of Contaminated Land to Buildings, Building Materials and Services: A Literature Review. Technical Report P331. EA, 2000. (INFO-RA2-6b) (PDF, 464KB)
  • Assessment and Management of Risks to Buildings, Building Materials and Services from Land Contamination. Technical Report P5 035/TR/01. EA, 2001. (INFO-RA2-6c) (PDF, 10.5MB)
  • Approved document C - Site preparation and resistance to contaminants and moisture. ODPM, 2010 (INFO-RA2-6d) (PDF, 2.7MB)
  • Designing Drains and Sewers for Brownfield Sites, British Plastics Federation, 2018. (PDF, 450KB)
  • Invasive Weed Control Technical Document Library - Property Care Association

Assessing risks to ecosystems (INFO-RA2-5)

A number of regulatory regimes now require an ecological risk assessment (ERA) to be carried out. All these regimes are concerned, in one way or another, with assessing the risk of significant harm to an organism, an animal or a whole ecosystem. To ensure consistency in ERA, Defra and the EA have developed an ERA framework for use in land quality assessments.

ERA framework

The framework offers a series of tiered activities, decisions and actions that provide a practical match between available resources and the severity of a land contamination problem. It allows decisions to be made rationally, consistently and transparently and forms the basis for discussions between the relevant parties (these may include: site owners, regulatory authorities and the local community).

  • Main report: An ecological risk assessment framework for contaminants in Soil (SC070009/SR1) (PDF, 6.8MB) - September 2008
  • Summary: ecological risk assessment (PDF, 57KB) - October 2008

ERA guidance

  • Assessing Risks to Ecosystems from Land Contamination. R&D Technical Report P299. EA, 2002. (INFO-RA2- 5a) (PDF, 8MB)
  • Review of Sublethal Ecotoxicological Tests for Measuring Harm in Terrestrial Ecosystems, P5-063/TR1. EA, 2002. (INFO-RA2-5b) (PDF, 10MB)
  • Ecological Risk Assessment, R&D Technical Report P5-069/TR1. EA, 2003. (INFO-RA2-5c) (PDF, 600KB) - Dec 2003
  • Soil Screening Values for use in Ecological Risk Assessment R&D Technical Report P5-091/TR. EA, 2004. (INFO-RA2-5d) (PDF, 707KB)
  • Guidance on desk studies and conceptual site models for ecological risk assessment (PDF, 7MB) - October 2008
  • Guidance on the use of Soil Screening Values for Ecological Risk Assessment (PDF, 6.3MB) - October 2008
  • Guidance on the use of Bioassays in Ecological Risk Assessment (PDF, 6.3MB) - October 2008
  • Guidance on the attribution of Cause and Effect in Ecological Risk Assessment (PDF, 6KB) - October 2008
  • Guidance on the use of Ecological Surveys in Ecological Risk Assessment (PDF, 6.4MB) - October 2008
  • Soil Screening Values for Assessing Ecological Risk: Summary - (PDF, 134KB) - November 2017
  • Derivation and Use of Soil Screening Values for Assessing Ecological Risk: Report - (PDF, 1.15MB) - November 2017
  • Soil Screening Values for Assessing Ecological Risk: Tool - (MS Excel Spreadsheet) - November 2017

CL:AIRE

RB 12 - Modelling Food-Chain Transfer of Contaminants in Soil to Terrestrial Ecological Receptors (2010)

Assessing risks to human health (INFO –RA2-2)

Land contamination can affect the health of people living, working, visiting or otherwise present on a site. The risk assessment process is used to establish whether there is an unacceptable risk to humans.

Contaminated Land Exposure Assessment (CLEA)

    • Human health toxicological assessment of contaminants in soil (Science Report Final SC050021/SR2) (PDF, 718KB)
      This report describes the technical principles and framework the EA use to derive Health Criteria Values.
    • Updated technical background to the CLEA model (Science Report Final SC050021/SR3) (PDF, 1.60MB)
      This report describes the technical background to the CLEA model. It also sets out the underlying assumptions that the EA have made to predict exposure for three standard land use scenarios (residential, allotments and commercial).
    • Environment Agency Science Reports relevant to CLEA

CLEA Software and Handbook

      • CLEA software v 1.071
      • CLEA software v 1.06
      • CLEA Licence Agreement
      • CLEA handbook v 1.05

        The CLEA software version 1.05 handbook is still relevant to version 1.06 and 1.071 and has not been changed.

Toxicological Reports (TOX) (INFO-RA2-2d)

      • TOX Reports for SGV derivation

Soil Guideline Values (SGVs) (INFO-RA2-2e)

      • Soil Guideline Values
      • Published SGVs

Category 4 Screening Levels (C4SL)

      • Category 4Screening Levels (C4SLs)

Generic Screening Values (GAC)

    • EIC/AGS/CL:AIRE Generic Assessment Criteria (GAC)
    • LQM/CIEH S4UL 
    • SoBRA: Development of Generic Assessment Criteria for Assessing Vapour Risks to Human Health from Volatile Contaminants in Groundwater

Bioaccessibility

      • Measurement of Bioaccessibility of Arsenic in UK Soils, P5-062/TR02, EA, 2002.(PDF, 72KB) (INFO-RA2-2f)
      • International workshop on the potential use of bioaccessibility testing in risk assessment of land contamination, Science Report SC040054, 2005
      • In-vitro Bioaccessisbility Testing: Current Science and Way Forward. Environment Agency Science Update 2, 2007
      • Environment Agency views on using in vitro bioaccessibility data in land contamination risk assessments for human health, June 2007
      • Additional bioaccessibility references are available from Science Reports relevant to CLEA

General Information 

      • Method for Deriving Site-specific Human Health Assessment Criteria for Contaminants in Soils, LQ01, SNIFFER, SEPA, EA, 2003. (INFO-RA2-2g)
      • Human Health Risk Assessment – Detailed Quantitative Risk Assessment, EA (No report produced). (INFO-RA2-2h)
      • The UK Approach for Evaluating the Human Health Risks from Petroleum Hydrocarbons in Soils EA, 2005 (PDF, 536KB)

TPH Working Group Series (TPHCWG) - Available through AEHS Foundation Online Store

      • Petroleum Hydrocarbon Analysis of Soil and Water in the Environment, Volume 1, TPHCWG, 1998. (INFO-RA2-2i)
      • Composition of Petroleum Mixtures, Volume 2, TPHCWG, 1998. (INFO-RA2-2j)
      • Selection of Representative TPH Fractions Based on Fate and Transport Considerations, Volume 3, TPHCWG, 1997. (INFO-RA2-2k)
      • Development of Fraction-specific Reference Doses (RfDs) and Reference Concentrations (RfCs) for TPHs, Volume 4, TPHCWG, 1997. (INFO-RA2-2l)
      • Human Health Risk-based Evaluation of Petroleum Release Sites: Implementing the Working Group’s Approach, Volume 5, TPHCWG, 1999. (INFO-RA2-2m)

Contaminated Land Reports (CLR) - All withdrawn

      • CLR7 Overview of the Development of Guideline Values and Related Research, DEFRA/EA, 2002. (INFO-RA2-2a) Withdrawn.
      • CLR8 Priority Contaminants Report, DEFRA/EA, 2020.Withdrawn.
      • CLR9 Contaminants in Soils: Collation of Toxicological Data and Intake Values for Humans. Consolidated Main Report, CLR 9 DEFRA/EA, 2002. (INFO-RA2-2b). The Environment Agency completely re-wrote the old CLR9 report (now called the Human health toxicological assessment of contaminants in soil (Science Report Final SC050021/SR2)) to take account of Defra's ‘Way Forward’ exercise on Soil Guideline Values and other changes to the underlying science.
      • CLR 10 The Contaminated Land Exposure Assessment Model (CLEA): Technical Basis and Algorithms. DEFRA/EA, 2002. (INFO-RA2-2c). This has been withdrawn and rewritten as CLEA.

Assessing risks to the water environment (INFO-RA2-3)

Land contamination can affect groundwater, freshwater and coastal waters. Groundwater is particularly vulnerable to contamination as it underlies many sites and is difficult to clean up once polluted.

CIRIA

  • Contaminated Land Risk Assessment. A guide to good practice (C552). CIRIA. 2001.

CONCAWE

  • Environmental fate & effects of poly and perfluoroalkyl substances (PFAS). Report No. 8/16. Concawe. 2016.

CL:AIRE

  • Petroleum Hydrocarbons in Groundwater: Guidance on assessing petroleum hydrocarbons using existing hydrogeological risk assessment methodologies. CL:AIRE, 2017.
  • An Illustrated Handbook of LNAPL Transport and Fate in the Subsurface. CL:AIRE, 2014. (PDF, 16.7MB)
  • RB 08 - Modelling approaches for assessing risks associated with petroleum hydrocarbon spills in the UK Chalk aquifer (2009)
  • TB 11 - A practical guide to investigating DNAPL releases in the subsurface (2004)
  • TB 15 - Accounting for the groundwater-surface water interface in contaminated land assessments (2011)

Department of the Environment

  • CLR 1, A Framework for Assessing the Impact of Contaminated Land on Groundwater and Surface Water. DoE, 1994. Volume 1 (PDF, 35MB) (INFO-RA2-3a)
  • CLR1, A Framework for Assessing the Impact of Contaminated Land on Groundwater and Surface Water. DoE 1994 Volume 2 (PDF, 35MB) (INFO-RA2-3a)

Environment Agency

  • Groundwater protection: Principles and practice (GP3) EA 2012 - Superseded
  • The Environment Agency's Approach to Groundwater Protection (GP3) EA 2017 v1.0
  • Guidance on the Assessment and Interrogation of Subsurface Analytical Contaminant Fate and Transport Models, NC/99/38/1 EA, 2002 (PDF, 151MB) (INFO-RA2-3d)
  • Methodology for the Derivation of Remedial Targets for Soil and Groundwater to Protect Water Resources, R&D Publication 20. EA, 1999. (INFO-RA2-3c) - Superseded
  • Remedial Targets Methodology: Hydrogeological Risk Assessment for Land Contamination, 2006 (PDF, 107KB)
  • User manual v3.1 (PDF, 99KB)
  • Hydrogeological risk assessment for land contamination: Remedial targets Worksheet v3.2 (Excel, 714KB)

    The Remedial targets worksheet was updated by the Environment Agency in January 2013. This was to correct a formatting error on the level 3 groundwater sheet. In the Domenico Steady state mode - the ‘half life for degradation of contaminant in water’ box was blacked out despite being used in the calculations. The resulting default figure was not conservative. Version 3.2 is the updated version.

  • Land Contamination Groundwater Compliance Points: Quantitative Risk Assessments, EA, March 2017 (gov.uk web page)
  • Environment Agency Technical Advice to Third Parties on Pollution of Controlled Waters for Part 2A of the Environmental Protection Act 1990, No 07/02. EA, 2002. (INFO-RA2-3e)
  • ConSim (Release 2): Contamination Impact on Groundwater: Simulation by Monte Carlo Method. EA, 2003. (INFO-RA2-3f)
  • An Illustrated Handbook of DNAPL Transport and Fate in the Subsurface, R&D Publication 133. EA, 2004. (PDF, 788KB) (INFO-RA2-3g)
  • Piling and Penetrative Ground Improvement Methods on Land Affected by Contamination: Guidance on Pollution Prevention. NC99/73. EA, 2001.
  • Piling into Contaminated Sites, EA, 2002.
  • Piling in Layered Ground: Risks to Groundwater and Archaeology, Science Report SC020074/SR, 2006 (PDF 6.86MB)
  • Potential groundwater pollutants from cemeteries, EA, SCHO1204BIKR-E-P, ISBN: 1 84432 347 1, December 2004
     
  • Potential groundwater pollutants from cemeteries, EA - One page summary
  • Pollution Potential of Cemeteries - Draft Guidance, EA, R&D Technical report P223, ISBN: 1 85705 021 5, 2002
  • AMENDMENT to ‘Pollution potential of cemeteries’- R&D P223, EA, March 2004
  • Assessing the Groundwater Pollution Potential of Cemetery Developments, EA, SCHO0404BGLA-E-P, April 2004

SEPA

  • Guidance on Assessing the Impacts of Cemeteries on Groundwater, SEPA, LUPS GU 32, V3, dated 24/09/2015
  1. CLEA framework reports
  2. CLEA software and dioxins workbook
  3. CLEA software and handbook
  4. Dioxins site-specific worksheets

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